Radioactive Waste and its Management
Radioactive (or nuclear) waste is a byproduct from nuclear reactors, fuel processing plants, and institutions such as hospitals and research facilities. It also results from the decommissioning of nuclear reactors and other nuclear facilities that are permanently shut down.
Two broad classifications
High-level Waste - High-level radioactive waste results primarily from the fuel used by reactors to produce electricity
Low Level Waste - Low-level radioactive waste results from reactor operations and from medical, academic, industrial, and other commercial uses
Nuclear waste is the material that nuclear fuel becomes after it is used in a reactor. It looks exactly like the fuel that was loaded into the reactor -- assemblies of metal rods enclosing stacked-up ceramic pellets. But since nuclear reactions have occurred, the contents are’t quite the same
Before producing power, the fuel was mostly Uranium (or Thorium), oxygen, and steel. Afterwards, many Uranium atoms have split into various isotopes of almost all of the transition metals on your periodic table of the elements
The waste, sometimes called spent fuel, is dangerously radioactive, and remains so for thousands of years. When it first comes out of the reactor, it is so toxic that if you stood within a few meters of it while it was unshielded, you would receive a lethal radioactive dose within a few seconds and would die of acute radiation sickness within a few days
In practice, the spent fuel is never unshielded. It is kept underwater (water is an excellent shield) for a few years until the radiation decays to levels that can be shielded by concrete in large storage casks.
Options include deep geologic storage and recycling. The sun would consume it nicely if we could get into space, but since rockets are so unreliable, we can’t afford to risk atmospheric dispersal on lift-off.
Nuclear fuel and transformation
Nuclear reactors are typically loaded with Uranium Oxide fuel, UO2. Neutrons are introduced to the system, and many of them are absorbed by uranium atoms, causing them to become unstable and split, or fission, into two smaller atoms known as fission products
Sometimes, the uranium absorbs a neutron and does not fission, but rather transforms to a heavier isotope of uranium, such as U-239. U-239 beta-decays to Np-239, which in turn beta-decays to Pu-239. The heavier nuclide may then absorb another neutron to become an even heavier element. These heavier atoms are known as transuranics.
The radioactivity causes the spent nuclear fuel to continue emitting heat long after it has been removed from the reactor. A few of the radioactive isotopes in the mix of spent fuel are gaseous and need to be carefully contained so that they do not escape to the environment and cause radiation damage to living things
These heavier-than uranium, or "transuranic," elements do not produce nearly the amount of heat or penetrating radiation that fission products do, but they take much longer to decay.
Transuranic wastes, also called "TRU," therefore account for most of the radioactive hazard remaining in high-level waste after a thousand years
Composition of nuclear waste
Spent nuclear fuel composition varies depending on
- what was put into the reactor,
- how long the reactor operated, and
- how long the waste has been sitting out of the reactor
Most of the Uranium is still in the fuel when it leaves the reactor, even though its enrichment has fallen significantly. This Uranium can be used in advanced fast reactors as fuel and is a valuable energy source. The minor actinides, which include Neptunium, Americium, and Curium, are very long-lived nuclides that cause serious concern when it comes to storing them for more than 100,000 years. Fortunately, these are fissionable in fast reactors and can thus be used as fuel.
High and Low- level Waste
Radioactive isotopes will eventually decay, or disintegrate, to harmless materials. However, while they are decaying, they emit radiation. Some isotopes decay in hours or even minutes, but others decay very slowly. Strontium-90 and cesium-137 have half-lives of about 30 years (that means that half the radioactivity of a given quantity of strontium-90, for example, will decay in 30 years). Plutonium-239 has a half-life of 24,000 years.
High-level wastes are hazardous to humans and other life forms because of their high radiation levels that are capable of producing fatal doses during short periods of direct exposure
Reprocessing separates residual uranium and unfissioned plutonium from the fission products. The uranium and plutonium can be used again as fuel
Low-level wastes, which are generally defined as radioactive wastes other than high-level and wastes from uranium recovery operations, are commonly disposed of in near-surface facilities rather than in a geologic repository that is required for high-level wastes. There is no intent to recover the wastes once they are disposed of
Low-level waste includes items that have become contaminated with radioactive material or have become radioactive through exposure to neutron radiation. This waste typically consists of contaminated protective shoe covers and clothing, wiping rags, mops, filters, reactor water treatment residues, equipments and tools, luminous dials, medical tubes, swabs, injection needles, syringes, and laboratory animal carcasses and tissues. The radioactivity can range from just above background levels found in nature to much higher levels in certain cases such as parts from inside the reactor vessel in a nuclear power plant
Used Nuclear Fuel
With time, the concentration of fission fragments and heavy elements formed will increase to the point where it is no longer practical to continue to use the fuel. So after 18-36 months the used fuel is removed from the reactor. The amount of energy that is produced from a fuel assembly varies with the type of reactor and the policy of the reactor operator.
When removed from a reactor, the fuel will be emitting both radiation, principally from the fission fragments, and heat. It is unloaded into a storage pond immediately adjacent to the reactor to allow the radiation levels to decrease. In the ponds the water shields the radiation and absorbs the heat, which is removed by circulating the water to external heat exchangers. Used fuel is held in such pools for several months and sometimes many years. It may be transferred to naturally-ventilated dry storage on site after about five years.
Depending on policies in particular countries, some used fuel may be transferred to central storage facilities. Ultimately, used fuel must either be reprocessed or prepared for permanent disposal. The longer it is stored, the easier it is to handle
There are two alternatives for used fuel:
- reprocessing to recover and recycle the usable portion of it
- long-term storage and final disposal without reprocessing